The use of cheat codes in X-Men Origins: Wolverine on the PC involves editing a game file. As such, you should make sure you have a backup copy of the file to be edited before you make any changes. Should anything go wrong, you can simply replace the file with the copied original.
Need more information on editing game files? take a look at The Basics of Editing Computer Game Files.
Open the file WGame.ini in a text editor, such as Notepad (any text editor will do).
The default location of this file is My Documents \ Wolverine \ WGame \ Config \ WGame.ini.
Look for the following lines, and change their value from False to True to activate the cheat.
Changing the following line will activate God Mode.
Search for: mCombatHeroIsGod=False
Change to: mCombatHeroIsGod=True
Maxed Out /Unlock All Talents
Search for: mCheatTalentsMax=False
Change to: mCheatTalentsMax=True
Now, save the file and start the game. The cheats you set to true will be active.
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